Sigma Percentile

Nomenclature and Characterisation

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JEE Main 2026
LEVELJEE Advanced

Comprehension Passage

Consider the following reaction sequence in which J, K, L and M are the major products. Given: Atomic mass (in amu): H : 1, C : 12, N : 14, O : 16, S : 32, Br : 80, Ba : 137
Question 1:

The volume of 1 M aqueous required to completely neutralize the ammonia evolved from 5.72 g of L in Kjeldahl's method of nitrogen estimation is ____ mL.

Question 2:

In sulphur estimation by Carius method, the amount of formed from 3.79 g of M is ____ g.

JEE Advanced 2014
LEVELJEE Main

The correct combination of names for isomeric alcohols with molecular formula is/are-

* Multiple Correct Options
(A)
tert-butanol and 2-methylpropan-2-ol
(B)
tert-butanol and 1, 1-dimethylethan-1-ol
(C)
n-butanol and butan-1-ol
(D)
isobutyl alcohol and 2-methylpropan-1-ol
JEE Advanced 2015
LEVELJEE Advanced

The total number of stereoisomers that can exist for M is :

JEE Advanced 2020
LEVELJEE Main

Which one of the following structures has the IUPAC name 3-ethynyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid ?

(A)
(B)
(C)
(D)
JEE(Advanced) 2017
LEVELJEE Main

The IUPAC name(s) of the following compound is(are)

* Multiple Correct Options
(A)
4-methylchlorobenzene
(B)
4-chlorotoluene
(C)
1-chloro-4-methylbenzene
(D)
1-methyl-4-chlorobenzene
JEE Advanced 2020
LEVELJEE Advanced

The Fischer projection of D-erythrose is shown below. D-Erythrose and its isomers are listed as P, Q, R, and S in Column-I. Choose the correct relationship of P, Q, R, and S with D-erythrose from Column II.

List-I

(P)
P
(Q)
Q
(R)
R
(S)
S

List-II

(1)
Diastereomer
(2)
Identical
(3)
Enantiomer
JEE Advanced 2020
LEVELJEE Advanced

Newman projections P, Q, R and S are shown below : Which one of the following options represents identical molecules ?

(A)
P and Q
(B)
Q and S
(C)
Q and R
(D)
R and S
JEE Advanced 2022
LEVELJEE Advanced

Match the compounds in LIST-I with the observation in LIST-II, and choose the correct option.

List-I

(P)
Aniline
(Q)
o-Cresol
(R)
Cysteine
(S)
Coprolactam

List-II

(1)
Sodium fusion extract of the compound on boiling with , followed by acidification with conc. , gives Prussian blue color.
(2)
Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
(3)
Addition of the compound to a saturated solution of results in effervescence.
(4)
The compound reacts with bromine water to give a white precipitate.
(5)
Treating the compound with neutral solution produces violet color.
JEE Advanced 2018
LEVELJEE Advanced

For the given compound X, the total number of optically active stereoisomers is______.

JEE Main 2021
LEVELJEE Main

The number of acyclic structural isomers (including geometrical isomers) for pentene are ......... .

JEE Main 2020
LEVELJEE Main

The number of -hybridised carbons present in "aspartame" is ............

JEE Main 2020
LEVELJEE Main

The IUPAC name of the following compound is

(A)
3-bromo-5-methylcyclopentane carboxylic acid
(B)
3-bromo-5-methylcyclopentanoic acid
(C)
5-bromo-3-methylcyclopentanoic acid
(D)
4-bromo-2-methylcyclopentane carboxylic acid
JEE Main 2019
LEVELJEE Main

The correct match between Item-I and Item-II is\n\n

(A)
A R ; B P ; C S ; D Q
(B)
A R ; B S ; C P ; D Q
(C)
A Q ; B P ; C S ; D R
(D)
A Q ; B S ; C P ; D R
JEE Main 2015
LEVELJEE Main

Which of the following compound will exhibit geometrical isomerism?

(A)
1-phenyl-2-butene
(B)
3-phenyl-1-butene
(C)
2-phenyl-1-butene
(D)
1, 1-diphenyl-1-propane
JEE Main 2020
LEVELJEE Main

Which of the following compounds shows geometrical isomerism?

(A)
2-methylpent-2-ene
(B)
4-methylpent-2-ene
(C)
4-methylpent-1-ene
(D)
2-methylpent-1-ene
JEE Main 2021
LEVELJEE Main

The number of compound(s) given below which contain(s) — COOH group is ……… . (i) Sulphanilic acid (ii) Picric acid (iii) Aspirin (iv) Ascorbic acid

JEE Main 2021
LEVELJEE Main

Nitrogen can be estimated by Kjeldahl's method for which of the following compound ?

(A)
(B)
(C)
(D)
JEE Main 2019
LEVELJEE Main

If dichloromethane (DCM) and water () are used for differential extraction, which one of the following statements is correct?

(A)
DCM and would stay as lower and upper layer respectively in the S.F.
(B)
DCM and would stay as upper and lower layer respectively in the separating funnel (SF)
(C)
DCM and will be miscible clearly
(D)
DCM and will make turbid/colloidal mixture
JEE Main 2020
LEVELJEE Main

A flask contains a mixture of isohexane and 3-methylpentane. One of the liquids boils at while the other boils at . What is the best way to separate the two liquids and which one will be distilled out first?

(A)
Fractional distillation, 3-methylpentane
(B)
Fractional distillation, isohexane
(C)
Simple distillation, 3-methylpentane
(D)
Simple distillation, isohexane
JEE Main 2021
LEVELJEE Main

Which purification technique is used for high boiling organic liquid compound (decomposes near its boiling point)?

(A)
Simple distillation
(B)
Steam distillation
(C)
Fractional distillation
(D)
Reduced pressure distillation
JEE Main 2020
LEVELJEE Main

The Kjeldahl method of nitrogen estimation fails for which of the following reaction products?

(A)
III and IV
(B)
I and IV
(C)
I, III and IV
(D)
II and III
JEE Main 2019
LEVELJEE Main

What is the IUPAC name of the following compound ?

(A)
3-bromo-3-methyl-1, 2-dimethylprop-1-ene
(B)
3-bromo-1,2-dimethylbut-1-ene
(C)
2-bromo-3-methylpent-3-ene
(D)
4-bromo-3-methylpent-2-ene
JEE Main 2010
LEVELJEE Main

29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl's method and the evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid required 15 mL of 0.1 M NaOH solution for complete neutralization. The percentage of nitrogen in the compound is

(A)
59.0
(B)
47.4
(C)
23.7
(D)
29.5
JEE Main 2021
LEVELJEE Main

0.8 g of an organic compound was analysed by Kjeldahl's method for the estimation of nitrogen. If the percentage of nitrogen in the compound was found to be 42%, then ......... mL of would have been neutralised by the ammonia evolved during the analysis.

LEVELJEE Main

Amongst the following compounds, the optically active alkane having lowest molecular mass is

(A)
(B)
(C)
(D)